Data mining, particularly the analysis of multivariate time series data, plays a crucial role in extracting insights from complex systems and supporting informed decision-making across diverse domains. However, assessing the similarity of multivariate time series data presents several challenges, including dealing with large datasets, addressing temporal misalignments, and the need for efficient and comprehensive analytical frameworks. To address all these challenges, we propose a novel integrated computational approach known as Multivariate Time series Alignment and Similarity Assessment (MTASA). MTASA is built upon a hybrid methodology designed to optimize time series alignment, complemented by a multiprocessing engine that enhances the utilization of computational resources. This integrated approach comprises four key components, each addressing essential aspects of time series similarity assessment, thereby offering a comprehensive framework for analysis. MTASA is implemented as an open-source Python library with a user-friendly interface, making it accessible to researchers and practitioners. To evaluate the effectiveness of MTASA, we conducted an empirical study focused on assessing agroecosystem similarity using real-world environmental data. The results from this study highlight MTASA's superiority, achieving approximately 1.5 times greater accuracy and twice the speed compared to existing state-of-the-art integrated frameworks for multivariate time series similarity assessment. It is hoped that MTASA will significantly enhance the efficiency and accessibility of multivariate time series analysis, benefitting researchers and practitioners across various domains. Its capabilities in handling large datasets, addressing temporal misalignments, and delivering accurate results make MTASA a valuable tool for deriving insights and aiding decision-making processes in complex systems.